Near-Room-Temperature Magnetoelectric Coupling via Spin Crossover in an Iron(II) Complex

Magdalena Owczarek, Minseong Lee, Shuanglong Liu, Ella R. Blake, Chloe S. Taylor, Georgia A. Newman, James C. Eckert*, Juan H. Leal, Troy A. Semelsberger, Hai-Ping Cheng, Wanyi Nie, Vivien S. Zapf

Angewandte Chemie 136 (22), e202318220 (2024)

Abstract

Magnetoelectric coupling is achieved near room temperature in a spin crossover FeII molecule-based compound, [Fe(1bpp)2](BF4)2. Large atomic displacements resulting from Jahn–Teller distortions induce a change in the molecule dipole moment when switching between high-spin and low-spin states leading to a step-wise change in the electric polarization and dielectric constant. For temperatures in the region of bistability, the changes in magnetic and electrical properties are induced with a remarkably low magnetic field of 3 T. This result represents a successful expansion of magnetoelectric spin crossovers towards ambient conditions. Moreover, the observed 0.3–0.4 mC m−2 changes in the H-induced electric polarization suggest that the high strength of the coupling obtained via this route is accessible not just at cryogenic temperatures but also near room temperature, a feature that is especially appealing in the light of practical applications.