{"id":4763,"date":"2018-06-12T14:46:47","date_gmt":"2018-06-12T21:46:47","guid":{"rendered":"https:\/\/www.hmc.edu\/chemistry\/?page_id=4763"},"modified":"2022-10-13T11:12:51","modified_gmt":"2022-10-13T18:12:51","slug":"publications","status":"publish","type":"page","link":"https:\/\/www.hmc.edu\/chemistry\/faculty-staff\/van-heuvelen\/publications\/","title":{"rendered":"Katherine M. Van Heuvelen Publications and Presentations"},"content":{"rendered":"\n

Publications<\/h2>\n\n\n\n

(Undergraduate co-authors are denoted by an asterisk)<\/p>\n\n\n\n

23. “Emergency Remote Instruction during the COVID-19 Pandemic Reshapes Collaborative Learning in General Chemistry,”<\/a> K.M. Van Heuvelen, G.W. Daub, H. Van Ryswyk.  Journal of Chemical Education, 2020<\/strong>, 97 (9), 2884 \u2013 2888. <\/p>\n\n\n\n

22. “How do I design a reaction to do useful work? Reinvigorating general chemistry by connecting chemistry and society<\/a>,” K.M. Van Heuvelen, G.W. Daub, A.R. Johnson, L.N. Hawkins, H. Van Ryswyk, D.A. Vosburg.  Journal of Chemical Education, 2020<\/strong>, 97, 925-933. <\/p>\n\n\n\n

21. “Emphasizing Learning: The Impact of Student Surveys in the Reform of an Introductory Chemistry Course,<\/a>”  K.M. Van Heuvelen, L. Palucki Blake, G.W. Daub, A.R. Johnson, L.H. Hawkins, H. Van Ryswyk, D.A. Vosburg.  Journal of Assessment and Institutional Effectiveness, 2019<\/strong>, 9, 1-28. <\/p>\n\n\n\n

20. “Crystal Structure and Spectroscopic Characterization of a Cobalt(II) Tetraazamacrocycle: Completing a Series of First-Row Transition Metal Complexes<\/a>,” K.M. Van Heuvelen, I. Lee*, K. Arriola*, R. Griffin*, C. Ye*, M. Takase, Acta Crystallographica Section C, <\/em>2017<\/strong>, C73, 620-624.<\/p>\n\n\n\n

19. “Mononuclear Nickel(II) and Copper(II) Coordination Complexes Supported by Bispicen Ligand Derivatives: Experimental and Computational Studies<\/a>,” N. Singh, J. Niklas, O. Poluektov, K.M. Van Heuvelen, A. Mukherjee*, Inorganica Chimica Acta<\/em>, 2017<\/strong>, 455, 221-230.<\/p>\n\n\n\n

18. “Cobalt Kb Valence-to-Core X-ray Emission Spectroscopy: A Study of Low-Spin Octahedral Cobalt(III) Complexes<\/a>,” K. Schwalenstocker, J. Paudel, J.; A.W. Kohn, C. Dong, K.M. Van Heuvelen, E.R. Farquhar*, F. Li*, Dalton Transactions, <\/em>2016<\/strong>, 45, 14191-14202.<\/p>\n\n\n\n

17. “Characterization of a Heterobimetallic Nonheme Fe(III)-O-Cr(III) Species Formed by O2<\/sub> Activation<\/a>,” A. Zhou, S.T. Kleespies, K.M. Van Heuvelen, L. Que, Chemical Communications<\/em>, 2015<\/strong>, 51, 14326-14329.<\/p>\n\n\n\n

16. “Spectroscopic Identification of an FeIII<\/sup> Center, not FeIV<\/sup>, in the Crystalline Sc-O-Fe Adduct Derived from [FeIV<\/sup>(O)(TMC)]2+<\/sup><\/a>,” J. Prakash, G.T. Rohde, K.K. Meier, A.J. Jasniewski, K.M. Van Heuvelen, E. M\u00fcnck, L. Que, Am. Chem. Soc., <\/em>2015<\/strong>, 137, 3478-3481.<\/p>\n\n\n\n

15. “An Ultra-Stable Oxoiron(IV) complex and its Blue Conjugate Base<\/a>,” J. England, J.O. Bigelow, K.M. Van Heuvelen, E.R. Farquhar, M. Martinho, K.K. Meier, J.R. Frisch, E. M\u00fcnck, L. Que, Chem. Sci., <\/em>2014<\/strong>, 5, 1204-1215.<\/p>\n\n\n\n

14. “Sc3+<\/sup> can trigger the formation of an oxoiron(IV) complex from O2<\/sub> and its nonheme iron(II) precursor via a Sc3+<\/sup>-peroxo-Fe3+<\/sup> intermediate<\/a>,” F. Li, K.M. Van Heuvelen, K.M. Meier, J. England, E. M\u00fcnck, L. Que, Am. Chem. Soc.,<\/em> 2013<\/strong>, 135, 10198-10201.<\/p>\n\n\n\n

13. “Isolation and Characterization of a Thiolato-Iron(III)-Peroxy Anion Complex,<\/a>” A.R. McDonald, K.M. Van Heuvelen, Y. Guo, E. M\u00fcnck, L. Que, Angew. Chem. Int. Ed., <\/em>2012<\/strong>, 5<\/em>1, 9132-9136.<\/p>\n\n\n\n

12. “One-Electron Oxidation of an Oxoiron(IV) Complex to Form an [O=FeV<\/sup>=NR]+<\/sup> Center<\/a>,” K.M. Van Heuvelen, A.T. Fieder, X. Shan, R. DeHont, K.K. Meier, E. M\u00fcnck, L. Que, Proc. Nat. Acad. Sci., <\/em>2012<\/strong>, <\/em>109, 11933-1938.<\/p>\n\n\n\n

11. “A More Reactive Trigonal-Bipyramidal High-Spin Oxoiron(IV) Complex with a cis-Labile Site<\/a>,” J. England, Y. Guo, K.M. Van Heuvelen, M.A. Cranswick, G.T. Rohde, E.L. Bominaar, E. M\u00fcnck, L. Que, Am. Chem. Soc., <\/em>2011<\/strong>, 133, 11880-11883.<\/p>\n\n\n\n

10. “Characterization of a High-Spin Non-Heme FeIII<\/sup>-OOH Intermediate and Its Quantitative Conversion to an FeIV<\/sup>=O Complex<\/a>,” F. Li, K.K. Meier, M.A. Cranswick, M. Chakrabrti, K.M. Van Heuvelen, E. M\u00fcnck, L. Que, Am. Chem. Soc., <\/em>2011<\/strong>, 133, 7256-7259.<\/p>\n\n\n\n

9. “Spectroscopic and Computational Studies on High-Spin Ni(II) Thiolate Compounds<\/a>,” K.M. Van Heuvelen, J. Cho, T. Dingee, C.G. Riordan, T.C. Brunold, Inorg. Chem., <\/em>2010<\/strong>, 49, 6535-6544.<\/p>\n\n\n\n

8. “Spectroscopic and Computational Studies of the m\u2013h2<\/sup>:h2<\/sup>\u2013Disulfido\u2013Bridged Dinickel(II) Species [(PhTttBu<\/sup>)2<\/sub>Ni2<\/sub>(m\u2013h2<\/sup>:h2<\/sup>\u2013S2<\/sub>)]<\/a>,” K.M. Van Heuvelen, J. Cho, C.G. Riordan, T.C. Brunold, Inorg. Chem., <\/em>2010<\/strong>, 49, 3113-3120.<\/p>\n\n\n\n

7. “2(tmc)2<\/sub>(S2<\/sub>)](OTf)2<\/sub>: Comparison of End-on Disulfido and Peroxo Bonding in Ni(II) and Cu(II) Species<\/a>,” K.M. Van Heuvelen, M.T. Kieber-Emmons, C.G. Riordan, T.C. Brunold, Inorg. Chem., <\/em>2010<\/strong>, 49, 3104-3112.<\/p>\n\n\n\n

6. “Synthesis and Spectroscopic Characterization of a m-1,2-Disulfidodinickel Complex<\/a>,” M.T. Kieber-Emmons, K.M. Van Heuvelen, T.C. Brunold, C. G. Riordan, Am. Chem. Soc., <\/em>2009<\/strong>, 131, 440-441.<\/p>\n\n\n\n

5. “Computational Studies of Bioorganometallic Enzymes and Cofactors,” M.D. Liptak, K.M. Van Heuvelen, T.C. Brunold, In Metal Ions in Life Sciences Vol 6: Metal-Carbon Bonds in Enzymes and Cofactors. Eds. A. Sigel, H. Sigel, R.K.O. Sigel, Cambridge: Royal Society of Chemistry, 2009<\/strong>.<\/p>\n\n\n\n

4. “New Synthetic Routes to a Disulfido Dinickel(II) Complex: Characterization and Reactivity of a Ni2<\/sub>(m-h2<\/sup>:h2<\/sup>-S2<\/sub>) Core<\/a>,” J. Cho, K.M. <\/b>Van Heuvelen, G.P.A. Yap, T.C. Brunold, C.G. Riordan, Inorg. Chem.,<\/em> 2008<\/strong>, 47, 3931-3933.<\/p>\n\n\n\n

3. “Ferromagnetic Semiconducting EuO Nanorods<\/a>,” M.j. Bierman, K. M. Van Heuvelen, D. Schmei\u03b2er, T.C. Brunold, S. Jin, Adv. Mater.,<\/em> 2007<\/strong>, 19, 2677-2681.<\/p>\n\n\n\n

2. “Identification of an “End-On” Nickel-Superoxo Adduct, Ni(tmc)(O2<\/sub>)+<\/sup><\/a>” M.T. Kieber-Emmons, J. Annaraj, M.S. Seo, K.M. Van Heuvelen, T. Tosha, T. Kitagawa, T.C. Brunold, W. Nam, C.G. Riordan, Am. Chem. Soc.,<\/em> 2006<\/strong>, 128, 14230-14231.<\/p>\n\n\n\n

1. “Spectroscopic and Computational Studies of Reduction of the Metal versus the Tetrapyrrole Ring of Coenzyme F-430 from Methyl-Coenzyme M Reductase Dey<\/a>,” M. Dey, R.C. Kunz, K.M. Van Heuvelen, J.L. Craft, Y.C. Horng, Q. Tang, D.F. Bocian, S.J. George, T.C. Brunold, S.W. Ragsdale, Biochemistry<\/em>, 2006<\/strong>, 45, 11915-11933.<\/p>\n\n\n\n

Presentations<\/h2>\n\n\n\n

“Nickel(II) borohydride converts perchloroethylene to trichloroethylene,” Van Heuvelen, K.M. American Chemical Society National Meeting, Virtual, DIV: Inorg, April 2021.<\/p>\n\n\n\n

“How do I design a chemical reaction to do useful work, and how does my reaction impact society? A case study in reimaging general chemistry,” Van Heuvelen, K.M. American Chemical Society National Meeting, San Diego, CA, August 2019.<\/p>\n\n\n\n

“Assessing Introductory Courses: Creating Conversations about Learning through Student Surveys,” Van Heuvelen, K.M. and Palucki Blake, L., HEDS Conference, Spokane, WA, June 2018.<\/p>\n\n\n\n

“Bio-inspired dehalogenation: Developing first-row transition metal complexes to treat priority pollutants perchloroethylene and trichloroethylene,” in \u201cWomen in Inorganic Chemistry: Synthetic Chemistry Addressing Challenges in Energy and the Environment\u201d symposium, Van Heuvelen, K.M. American Chemical Society National Meeting, New Orleans, LA, March 2018 (invited speaker),<\/p>\n\n\n\n

“Designing Bio-Inspired Nickel and Cobalt Complexes to Treat Priority Pollutants,” Van Heuvelen, K.M. University of Wisconsin-Madison, Madison, WI, November 2017 (invited talk).<\/p>\n\n\n\n

“Crafting Your Career,” Van Heuvelen, K.M. University of Wisconsin-Madison, Madison, WI, November 2017 (invited talk).<\/p>\n\n\n\n

“Designing Bio-Inspired Nickel and Cobalt Complexes to Treat Priority Pollutants,” Van Heuvelen, K.M. University of La Verne, La Verne, CA, November 2017 (invited talk).<\/p>\n\n\n\n

“Bio-Inspired Dehalogenation: Developing First-Row Transition Metal Complexes to Treat Priority Pollutants,” Van Heuvelen, K.M.University of La Verne, La Verne, CA, April 2017 (invited talk).<\/p>\n\n\n\n

“Development of Bio-Inspired Catalysts for Dechlorination Reactions,” Gordon Research Conference: Metals in Biology Ventura, CA, January 2015 (poster).<\/p>\n\n\n\n

“Investigation of the Electronic Structure of Cobaloximes,” Van Heuvelen, K. M. Gordon Research Conference: Metals in Biology, January 2014, Ventura, CA (poster).<\/p>\n\n\n\n

“One-Electron Oxidation of an Oxoiron(IV) Complex,”Van Heuvelen, K. M.; Fiedler, A.T.; Meier, K.K.; DeHont, R.; Shan. X.; M\u00fcnck, E.; Que, L. International Conference of Bioinorganic Chemistry August 2011, Vancouver, British Columbia (poster).<\/p>\n\n\n\n

“One-Electron Oxidation of an Oxoiron(IV) Complex,”Van Heuvelen, K. M.; Fiedler, A.T.; Meier, K.K.; DeHont, R.; Shan. X.; M\u00fcnck, E.; Que, L. Gordon Research Conference: Metals in Biology, February 2011, Ventura, CA (poster).<\/p>\n\n\n\n

“Graduate School in Chemistry,”Van Heuvelen, K. M.<\/strong>St. Olaf College October 2010, Northfield, MN (invited seminar).<\/p>\n\n\n\n

“Insights into the Mechanism of Methyl-Coenzyme M Reductase: Spectroscopic and Computational Studies of Ni-C Bonding in Cofactor F430,”Van Heuvelen, K. M.; Dey, M.; Kunz, R.; Ragsdale, S. W.; Brunold, T. C. Gordon Research Seminar: Bioinorganic Chemistry, February 2009, Ventura, CA (talk).<\/p>\n\n\n\n

“Spectroscopic and Computational Studies of Ni\u2013Alkyl Bonding in the Active Site of Methyl-Coenzyme M Reductase,”Van Heuvelen, K. M.; Dey, M.; Kunz, R.; Ragsdale, S. W.; Brunold, T. C. Gordon Research Seminar: Bioinorganic Chemistry, February 2009, Ventura, CA (poster).<\/p>\n\n\n\n

“Spectroscopic and Computational Insights into Ni\u2013S Bonding in Methyl\u2013CoM Reductase and Synthetic Ni2<\/sub>(S2<\/sub>) Complexes,”Van Heuvelen, K. M.; Dey, M.; Kunz, R.; Kieber-Emmons, M. T.; Cho, J.; Riordan, C. G.; Ragsdale, S. W.; Brunold, T. C. Gordon Research Seminar: Bioinorganic Chemistry, February 2008, Ventura, CA (poster).<\/p>\n\n\n\n

“So You Want to Go to Grad School,”Van Heuvelen, K. M. St. Olaf College, September 2008, Northfield, MN (invited seminar).<\/p>\n\n\n\n

“Spectroscopic and Computational Studies of Ni-Containing Enzymes: Application to Acetyl-CoA Synthase\/Carbon Monoxide Dehydrogenase and Methyl-Coenzyme M Reductase,”Van Heuvelen, K. M.; Dey, M.; Kunz, R.; Kieber-Emmons, M. T.; Riordan, C. G.; Ragsdale, S. W.; Brunold, T. C. International Conference of Biological Inorganic Chemistry, August 2005, Ann Arbor, MI (poster).<\/p>\n\n\n\n

“Modeling Enzyme Active Sites: Synthesis of Group VI Heterobimetallic Compounds,”Van Heuvelen, K. M.; Miessler, G. L. St. Olaf Summer Research Symposium, August 2002\/2003, Northfield, MN (talk).<\/p>\n\n\n\n

“Green Chemistry: Diels-Alder Reactions in Ionic Solutions,” Patterson, M.; Van Heuvelen, K. M.; Spessard, G. Poster presented at St. Olaf College May 2003, Northfield, MN (poster).<\/p>\n\n\n\n

“Modeling Enzyme Active Sites: Synthesis of Group VI Heterobimetallic Compounds,”Van Heuvelen, K. M.; Miessler, G. L. Pew Midstates Science and Mathematics Consortium, Fall 2003, Chicago, IL (talk).<\/p>\n","protected":false},"excerpt":{"rendered":"

Publications (Undergraduate co-authors are denoted by an asterisk) 23. “Emergency Remote Instruction during the COVID-19 Pandemic Reshapes Collaborative Learning in […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":183,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_acf_changed":false,"footnotes":""},"class_list":["post-4763","page","type-page","status-publish","hentry"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/pages\/4763","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/comments?post=4763"}],"version-history":[{"count":1,"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/pages\/4763\/revisions"}],"predecessor-version":[{"id":7564,"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/pages\/4763\/revisions\/7564"}],"up":[{"embeddable":true,"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/pages\/183"}],"wp:attachment":[{"href":"https:\/\/www.hmc.edu\/chemistry\/wp-json\/wp\/v2\/media?parent=4763"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}